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The partitioning behavior of indium and thallium ions between aqueous hydrochloric acid solutions and hydrophobic betainium bis trifluoromethylsulfonylimide ionic liquid was studied using a standard liquidliquid extraction technique. The ionic liquid 1-butyl-3-methylimidazolium bis trifluoromethylsulfonylimide Bmim NTf 2 combined with the diglycolamide extractant NN -dioctyldiglycolamic acid DODGAA was adsorbed on macroporous resin support to produce a solvent impregnated resin SIR that was investigated for separations of 225 Ac and lanthanides.
Methyltri-n-octylammonium bistrifluoromethanesulfonylimide Trioctylmethylammonium bistrifluoromethylsulfonylimide Empirical Formula Hill Notation.
Bis trifluoromethylsulfonyl imide acid. Methyltri-n-octylammonium bistrifluoromethanesulfonylimide Trioctylmethylammonium bistrifluoromethylsulfonylimide Empirical Formula Hill Notation. C 27 H 54 F 6 N 2 O 4 S 2 Molecular Weight. Triethylsulfonium Bistrifluoromethanesulfonylimide C8H15F6NO4S3 CID 16211135 - structure chemical names physical and chemical properties classification patents literature biological activities safetyhazardstoxicity information supplier lists and more.
N-H acid bistrifluoromethylsulfonyl imide henceforth named HTf 2 N is a hygroscopic white solid which is soluble in organic solvents such as benzene or dichloromethane. In organic synthesis new reactions between HTf 2 N and carbodiimides allow the synthesis of. Aqueous N-H acid bistrifluoromethylsulfonyl imide Solution - C4mimTf2N Ionic Liquid Biphasic System.
An Original Investigation by Diffusion Ordered Spectroscopy Nuclear Magnetic Resonance. Journal of Fluorine Chemistry 2021 245 109782. According to the harmonised classification and labelling ATP01 approved by the European Union this substance is toxic if swallowed is toxic in contact with skin causes severe skin burns and eye damage may cause damage to organs through prolonged or repeated exposure and is harmful to aquatic life with long lasting effects.
Lithium bis trifluoromethanesulfonylimide often simply referred to as LiTFSI is a hydrophilic salt with the chemical formula LiC 2 F 6 NO 4 S 2. It is commonly used as Li-ion source in electrolytes for Li. Find related products papers technical documents MSDS more at Sigma-Aldrich.
CID 157857 111-Trifluoro-N- trifluoromethylsulfonylmethanesulfonamide Date s. Bistriflylimide anion is an imide anion in which the substituents on the negatively charged nitrogen are triflyl groups. 1-Hexadecyl-3-methylimidazolium bistrifluoromethylsulfonylimide is a solid-phase ionic organic material under ambient temperature and is considered as a kind of frozen ionic liquid.
Because of their solid-state and ultra-hydrophobicity frozen ionic liquids are able to be confined in the pores of hollow fiber based on which a simple method was developed for the hollow-fiber solid-phase microextraction. The noteworthy features of this study are the preparation of stable arenediazonium bis trifluoromethylsulfonylimide salts that can be used with no significant loss activity after 1 week and bis trifluoromethanesulfonamide was recovered in high yields from reactions. The partitioning behavior of indium and thallium ions between aqueous hydrochloric acid solutions and hydrophobic betainium bis trifluoromethylsulfonylimide ionic liquid was studied using a standard liquidliquid extraction technique.
The experiments were mainly carried out by means of a radiochemical method using 111 In and 201 Tl medical. The ionic liquid 1-butyl-3-methylimidazolium bis trifluoromethylsulfonylimide Bmim NTf 2 combined with the diglycolamide extractant NN -dioctyldiglycolamic acid DODGAA was adsorbed on macroporous resin support to produce a solvent impregnated resin SIR that was investigated for separations of 225 Ac and lanthanides. Its name is 1-Ethyl-3-Methylimidazolium BisTrifluoromethylsulfonylImide Chemsrc provides CAS174899-82-2 MSDS density melting point boiling point structure etc.
Densities of two selected ionic liquids ILs 1-butyl-3-methylimidazolium bistrifluoro-methylsulfonylimide bmimNTf2 and 1-butyl-1-methylpyrrolidinium bistrifluoromethyl-sulfonylimide bmpyrNTf2 were determined in the temperature range from 29315 to 35315 K. From the experimental density values the thermal expansion coefficient was calculated. Magnesium bistrifluoromethylsulfonylimide is a strong Lewis acid and used as a catalyst in organic synthesis.
It is an electrolyte which shows high anodic stability. This leads to the presence of proton donor and acceptor sites such that a hydrogen bond network is developed 14. In this study bis trifluoromethylsulfonyl imide acid HTf 2 N was used as the Brønsted acid and hexylethylenediamine Hexen was the Brønsted base.
Lithium bis trifluoromethylsulfonylimide is used in the preparation of chiral imidazolium salt through an anion metathesis of the corresponding triflate organic electrolyte-based lithium batteries. It finds application in the preparation of rare-earth Lewis acid catalysts.